Journal
JOURNAL OF SOLID STATE CHEMISTRY
Volume 178, Issue 8, Pages 2555-2573Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2005.07.009
Keywords
gas-occlusion properties; transition metal carboxylate polymer complex; self-assembly; metalloporphyrin; microporous material; olefin hydrogenation; hydrogen exchange reactions
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Copper(II) terephthalate is the first transition metal complex found capable of adsorbing gases. This complex has opened the new field of adsorbent complex chemistry. It is recognized as the lead complex in the construction of microporous complexes. This specific system has been expanded to a systematic series of derivatives of other isomorphous transition metals, molybdenum(II), ruthenium(II, III), and rhodium(II). These complexes with open frameworks are widely recognized as very useful materials for applications to catalysis, separation at molecular level, and gas storage. (c) 2005 Elsevier Inc. All rights reserved.
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