Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 347, Issue 10, Pages 1379-1388Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200505065
Keywords
functionalized dendrimers; hydroformylation; immobilization; mesoporous silica; rhodium; supported catalysts
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Polyamidoamine (PAMAM) dendrimers up to the third generation were grown for the first time on the surface of a large-pore (18 nm) Davisil silica support. The supported dendrimers of generations 0, 1, 2 and 3 were phosphinomethylated and complexed with rhodium. All the generations were found to be very active for the hydroformylation of olefins. The hydroformylation of 1-octene was accomplished with a turnover frequency of 1700 h(-1) at 70 degrees C. The G(1) material was found to be the most active when the different generations were compared at 50% conversion at 70 degrees C.
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