Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 15, Issue 8, Pages 1277-1284Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.200400594
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Copper nanocrystals with plate-like morphologies and face-centered cubic (fcc) structures have been synthesized in mixed reverse micelles with a large excess of reducing agent. High-resolution transmission electron microscopy images and image simulations show the presence of multiple twin defects parallel to the (111) surface responsible for the forbidden reflections 1/3{422} of the fcc structure. A growth process related to the formation of twin defects is proposed to explain the existence of these morphologies.
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