Journal
TETRAHEDRON LETTERS
Volume 46, Issue 31, Pages 5131-5134Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.05.123
Keywords
sulfinylamine; anodic oxidation; diastereoselective alkylation; pelletierine
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The anodic oxidation of some chiral non-racemic N-arylsulfinyl piperidines was investigated and for the first time alpha methoxylated sulfinyl piperidines were obtained. The so-formed compounds are equivalent of chiral N-sulfinyliminiums and used as new intermediates for the preparation of chiral alpha-substituted piperidine derivatives in good yield and diastereoselectivity. (c) 2005 Elsevier Ltd. All rights reserved.
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