Journal
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS
Volume 61, Issue -, Pages 429-434Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S0108768105016083
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The bond-valence parameters (R-ij), which connect bond valences and bond lengths, have been computed for lanthanide-nitrogen bonds. It has been found that values of bond-valence parameters decrease with increasing lanthanide atomic number in coordination compounds, and that they are smaller than the R-ij parameters of inorganic compounds. As expected, the lanthanide-nitrogen bond-valence parameters are larger than lanthanide-oxygen bond-valence parameters. There are no obvious dependencies between the number of N atoms in the coordination sphere and the bond-valence parameter value.
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