4.5 Article

Cu-Al-Fe layered double hydroxides with CO32- and anionic surfactants with different alkyl chains in the interlayer

Journal

SOLID STATE SCIENCES
Volume 7, Issue 8, Pages 931-935

Publisher

ELSEVIER
DOI: 10.1016/j.solidstatesciences.2005.03.003

Keywords

hybrid organic-inorganic compounds; layered double hydroxides; anionic surfactant; Jahn-Teller effect

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Layered double hydroxides (LDHs), with the hydrotalcite-like structure containing Cu(II), Al(III) and Fe(III) in the layers, and different alkyl sulfonates in the interlayer, have been prepared and characterized by powder X-ray diffraction, FT-IR spectroscopy, differential thermal analysis and thermogravimetric analysis. Pure crystalline phases have been obtained in all cases. Upon heating, combustion of the organic chain takes place at lower temperature than the corresponding sodium salts. (c) 2005 Elsevier SAS. All rights reserved.

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