Journal
ORGANIC LETTERS
Volume 7, Issue 16, Pages 3453-3455Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0510872
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[GRAPHICS] Treatment of tertiary formamides with a silylated diazoester in the presence of a rhodium(11) catalyst leads to the formation of 3-amino-2-silyloxyacrylates in good yield. No olefination is observed if a nonsilylated diazo compound is employed.
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