Journal
ORGANIC LETTERS
Volume 7, Issue 16, Pages 3421-3424Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol051043t
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- NCI NIH HHS [CA 10143 8] Funding Source: Medline
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[GRAPHIC] An efficient, convergent synthesis of the core bicyclo[4.3.1]decane ring system of welwitindolinones is described. Key steps in the synthesis include an intramolecular palladium-catalyzed enolate arylation reaction to create the desired bicyclic skeleton and a Curtius rearrangement to install the bridgehead isocyanate unit.
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