Journal
ORGANIC LETTERS
Volume 7, Issue 16, Pages 3577-3579Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0515199
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Retro-allylation of bulky gallium homoallylic alkoxides occurs to generate (Z)- and (E)-crotylgallium reagents stereospecifically, starting from erythro- and threo-homoallylic alcohols, respectively. The (Z)- and (E)-crotylgallium reagents immediately reacted with aromatic aldehydes to afford the corresponding erythro- and threo-homoallylic alcohols, respectively.
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