Stable isotope study of cave percolation waters in subtropical Brazil: Implications for paleoclimate inferences from speleothems

We analyze the interannual monthly variability of oxygen isotope ratios in data from IAEA stations along the Atlantic coast of South America between 23 degrees and 34 degrees S to evaluate the influence of parameters such as temperature, rainfall amount and moisture source contribution on meteoric water recharging two karst systems in subtropical Brazil. In addition, a 2 year monitoring program performed on soil and cave drip and rimstone pool waters from sampling sites with contrasting discharge values and located at 100 and 300 m below the surface in the Santana Cave System (24 degrees 31' S; 48 degrees 43' W), is used to test the influence of hydrologic and geologic features on the temporal variations of seepage water delta O-18. Interannual monthly variations in delta O-18 of rainfall reflect primarily regional changes in moisture source contribution related to seasonal shifts in atmospheric circulation from a more monsoonal regime in summer (negative values of delta O-18) to a more extratropical regime in winter (positive values of delta O-18). Variations in groundwater delta O-18 indicate that the climatic signal of recent rainfall events is rapidly transmitted through the relatively deep karst aquifer to the cave drip waters, regardless of location of collection in the cave. In addition, the data also suggest that water replenishment in the system is triggered by the increase in hydraulic head during periods when recharge exceeds the storage capacity of the soil and epikarst reservoirs. Significant perturbations in the groundwater composition, characterized by more positive values of delta O-18, are probably connected to an increased Atlantic moisture contribution associated with extratropical precipitation. This implies that the delta O-18 of speleothems from caves in this region may be a suitable proxy for studying tropical-extratropical interactions over South America, a feature that is intrinsically related to the global atmospheric circulation. (c) 2005 Elsevier B.V. All rights reserved.