4.4 Article

Template-assisted control of porphyrin aggregation by ladder-type supramolecular assemblies

Journal

TETRAHEDRON LETTERS
Volume 46, Issue 32, Pages 5347-5350

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.06.001

Keywords

porphyrin; aggregate; ladder-type assembly; template; hydrogen bonding

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A new strategy to control the orientation and aggregation numbers of porphyrins by alignment along well-defined templates has been demonstrated. Porphyrin-bridged bisPYBOX ligands were arranged along the oligomeric secondary dialkylammonium cations as templates to form well-defined supramolecular complexes. The templates controlled the aggregations of the porphyrins. (c) 2005 Elsevier Ltd. All rights reserved.

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