Journal
TETRAHEDRON
Volume 61, Issue 32, Pages 7678-7685Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2005.05.097
Keywords
ionic liquid; porphyrin; condensation
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In place of widely used dichloromethane, a series of ionic liquids, ILs, was employed as a reaction medium for the one-flask preparation of tetraarylporphyrins. The porphyrin yield in the IL was comparable to that in the dichloromethane, as long as both the water content and the fluidity were conditioned to be in the optimum state. When acidic IL,[C-4-SAbim][CF3SO3] possessing a sulfonic acid moiety was used as the reaction medium, nothing but a black tarry by-product was obtained due to its strong acidity. However, using the acidic IL in a biphasic mode together with dichloromethane, enabled porphyrins to form, even at a high reactant concentration. Furthermore, the phase-separated acidic IL was reusable for at least 10 times without any loss of catalytic activity. (c) 2005 Elsevier Ltd. All rights reserved.
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