Journal
CHEMISTRY OF MATERIALS
Volume 17, Issue 16, Pages 4149-4153Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm049020g
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Many studies have been carried out concerning the development of SO2 sensors to detect and avoid its health prejudicial effects. However, there is still a lack of reliable, high-speed-response sensors that work at room temperature. In this work, the segregation of Ni in the SnO2-NiO system is used to obtain a rapid SO2 sensor response. Segregation and its structure consequences were studied by electron dispersive spectroscopy, infrared spectroscopy, and high-resolution transmission electron microscopy in nanopowders of SnO2-NiO with different compositions prepared by a polymeric precursor method. The sensor activity of SnO2-1 mol % Ni was studied and a linear calibration curve was formed with a maximum limit response of 32 PPM SO2.
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