4.4 Article

A simple route to novel functionalized tetrathiafulvalene vinylogues

Journal

TETRAHEDRON LETTERS
Volume 46, Issue 33, Pages 5499-5502

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.06.056

Keywords

dithiafulvene; tetrathiafulvalene; oxidative coupling; Diels-Alder

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The synthesis and X-ray structural determination of vinylogous tetrathiafulvalenes (TTFV) bearing functional groups on the central conjugation are reported. An unexpected evolution of the bis hydroxymethyl TTFV leading to a derivative, which acts simultaneously as a diene and a dienophile in a Diels-Alder reaction is also described. (c) 2005 Elsevier Ltd. All rights reserved.

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