Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 399, Issue 1-2, Pages 276-279Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2005.03.041
Keywords
filled skutterudite compounds; mechanical alloying; thermoelectric property; figures of merit Z
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LayFexCo4-x,Sb-12 skutterudites with different La filling content (y=0.2, 0.4, 0.6, 0.9;x=1.0) were prepared by mechanical alloying and hot pressing. The effect of La partially filling on the thermoelectric properties of these compounds has been studied. The results showed that the LayFexCo4-xSb12 single phase skutterudite compounds could be obtained by a combination of a 10 h mechanical alloying and a subsequent hot pressing at 650 degrees C for 2 h. Electrical and thermal conductivities of La filled skutterudite LayFeCo3Sb12 decreased with increasing La filling fraction. The Seebeck coefficient of LayFeCo3Sb12 became negative when y is 0.9. The figure of merit Z increased with La filling when the La content was not too high. The value Z of La0.6FeCo3Sb12 is larger than the other filled skutterudite compounds. (c) 2005 Elsevier B.V. All rights reserved.
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