Journal
ORGANIC LETTERS
Volume 7, Issue 17, Pages 3785-3787Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol051477o
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A triple helicate, having a macrocyclic aromatic amide structure, was synthesized in high yield because of a preorganized component of the tertiary benzenetrianilide moieties in a propeller-like syn conformation at both ends. The helicity was derived from tilted T-shaped aromatic-aromatic (CH-pi) interactions between each of the N-phenyl rings.
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