4.7 Article

Synthesis and structural characterization of a nonplanar neutral [36]metallacrown-12 nickel compound [Ni(C13H9N3O2)(CH3OH)]12

Journal

INORGANIC CHEMISTRY
Volume 44, Issue 17, Pages 5972-5974

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic0506254

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A nonplanar metallacrown [Ni-N-N]12 was achieved using a pentadente ligand, salicylaldehyde 2-pyridinecarboxylhydrazone (H2L) via a new modular self-assembly approach. The special bridging models of the ligand forced the macrocycle to form in a specific size with the wavelike conformation.

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