Journal
TETRAHEDRON
Volume 61, Issue 34, Pages 8226-8230Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2005.06.026
Keywords
pyrrole; indolizidines; alkaloids; gamma-lactones
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The nucleophilicity of pyrrole has been exploited to rapidly assemble the bicyclic skeleton of the indolizidine alkaloids. The key sequence is the annulation of a second ring onto pyrrole from a gamma-lactone and has been exploited in the synthesis of the natural products monomorine and (+/-)-indolizidine 209D. (c) 2005 Elsevier Ltd. All rights reserved.
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