Journal
JOURNAL OF POWER SOURCES
Volume 146, Issue 1-2, Pages 555-558Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2005.03.060
Keywords
phospho-olivine LiFePO4; hydrothennal synthesis; rechargeable lithium batteries; cathode materials; Raman spectroscopy
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Phospho-olivine LiFePO4 as a cathode material of rechargeable lithium battery was synthesized from LiOH, FeSO4, and (NH4)(3)PO4 by hydrothermal process at 170 degrees C. The optimized molar ratio of Li:Fe:P in the starting solution was 2.5:1:1. The charge and discharge capacities at 3.5 V versus Li/Li+ of hydrothermally synthesized LiFePO4 were 65 mAh g(-1). The additional heat treatment was carried out to improve the charge-discharge performance of hydrothermally synthesized LiFePO4. Raman spectroscopy revealed that existence of alpha-Fe2O3 on the particle surface of LiFCPO4 annealed at 400 degrees C. The charge and discharge capacities of the annealed LiFePO4 were 150 mAh g-1. Two plateaus at 3.5 and 2.5 V were observed in the charge-discharge curves, and the 2.5 V plateau was correlated with the Li+ insertion into alpha-Fe2O3. (c) 2005 Elsevier B.V. All rights reserved.
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