Journal
JOURNAL OF POWER SOURCES
Volume 146, Issue 1-2, Pages 281-286Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2005.03.029
Keywords
lithium-ion secondary battery; cathode materials; solid solutions with layered structure; phase diagram; design equations
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A new phase diagram of AB(CD)(1/2) system, where A, B, C, and D represent Li2MnO3, LiMO2 (M=Co, Al, Cr, etc.), LiMnO2, and LiM'O-2 (M'=Ni, Cu, Fe, etc.), respectively, was developed to express all compositions of solid solutions with layered manganese oxides. The phase diagram satisfied the theoretical manganese oxidation state of +4 over the whole triangle plane of the diagram and was expressed with a new design equation of Li[M-x(Li1/3Mn2/3)(y)(M'Mn-1/2(1/2))(1-x-y)]O-2 Solid solutions whose compositions were randomly chosen from the phase diagram were experimentally prepared using a direct synthetic method and were subjected to the examination of the structural and electrochemical properties. All the synthesized solid solutions had layered structure with maintaining +4 and showed one-step monotonous discharge curve shape without structural transformation during charge/discharge processes. (c) 2005 Elsevier B.V. All rights reserved.
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