Journal
LANGMUIR
Volume 21, Issue 18, Pages 8081-8084Publisher
AMER CHEMICAL SOC
DOI: 10.1021/la051117+
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Self-exchange of isotopically labeled polycarboxylic acid within a polyelectrolyte multilayer proceeds to completion and is reversible. Similar exchange with poly(styrene sulfonate), which forms nonlabile polyelectrolyte complexes, is slow and irreversible but is facilitated by polyvalent ion pairing interventions of a third polyelectrolyte. This is an example of accelerated kinetics in sticky synthetic systems associated by nonspecific polyvalent interactions.
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