Adsorption characteristics of malachite green on activated carbon derived from rice husks produced by chemical-thermal process

Phosphoric acid (H3PO4) and sodium hydroxide (NaOH) treated rice husks, followed by carbonization in a flowing nitrogen were used to study the adsorption of malachite green (MG) in aqueous solution. The effect of adsorption on contact time, concentration of MG and adsorbent dosage of the samples treated or carbonized at different temperatures were investigated. The results reveal that the optimum carbonization temperature is 500 degrees C in order to obtain adsorption capacity that is comparable to the commercial activated carbon for the husks treated by H3PO4. It is interesting to note that MG adsorbed preferably on carbon-rich than on silica rich-sites. It is found that the behaviour of H3PO4 treated absorbent followed both the Langmuir and Freundlich models while NaOH treated best fitted to only the Langmuir model. (c) 2005 Elsevier Ltd. All rights reserved.