Journal
ORGANIC LETTERS
Volume 7, Issue 18, Pages 4041-4043Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol051564g
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A [Ti(TADDOLato)] complex (1) catalyzes the enantioselective sulfenylation of beta-ketoesters using phenylsulfenyl chloride, giving ees of up to 88% and yields of up to 95%. The reaction does not require the presence of a base.
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