Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 690, Issue 17, Pages 3963-3969Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2005.05.038
Keywords
Suzuki coupling; cyclopalladated ferrocenylimines; tricyclohexylphosphine adducts; aryl chlorides; phenylboronic acid
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The air and moisture stable tricyclohexylphosphine (PCY3) adducts of dimeric cyclopalladated ferrocenylimines 5 and 6 have been easily synthesized and successfully used in palladium-catalyzed Suzuki cross-coupling of aryl chlorides. Using 0.1 mol% of 6 in the presence of 2 equivalent Of CS2CO3 as base in dioxane at 100 degrees C provided coupled products in excellent yields in the reaction of non-activated and deactivated aryl chlorides with phenylboronic acid. For activated chlorides such as 4-chloronitrobenzene and 4-chloroacetophenone, the catalyst loadings could be lowered to 0.01 mol% without loss of activity. (c) 2005 Elsevier B.V. All rights reserved.
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