Evaluation of hydrogen absorption properties of Ti-0.2 mass% Pd alloy in fluoride solutions

The hydrogen absorption properties of Ti-0.2 mass% pd (Ti-0.2Pd) alloy in 2.0% and 0.2% acidulated phosphate fluoride (APF) and neutral 2.0% NaF solutions (25 degrees C) has been evaluated by hydrogen thermal desorption analysis. During the early stage of immersion (120 h) in the 2.0% APF solution, the amount of absorbed hydrogen was lower than 500 mass ppm. A thermal desorption of hydrogen primary appearing with a peak at 500-600 degrees C and a broad desorption ranging from 100 to 400 degrees C were observed. In the 0.2% APF solution, the amount of absorbed hydrogen saturated at 100-200 mass ppm; the thermal desorption of hydrogen appeared with a single peak at 550 degrees C. In the 2.0% NaF solution, hydrogen absorption was negligible even after 1000 It of immersion, although corrosion pits were observed. The results of the present study suggest that the hydrogen absorption of Ti-0.2Pd alloy, as compared with commercial pure titanium, is suppressed in fluoride solutions. (c) 2005 Elsevier B.V. All rights reserved.