Journal
JOURNAL OF SOLID STATE CHEMISTRY
Volume 178, Issue 9, Pages 2658-2662Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2005.05.035
Keywords
metal phosphonates; structure; magnetic properties; thermal decomposition; cobalt(II); 2-(aminoethyl)phosphonic acid
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A tetrahedrally coordinated cobalt(II) phosphonate, CO(O3PCH2CH2NH2), has been synthesized using hydrothermal techniques. X-ray diffraction indicates that this material is a three-dimensional open framework with rings aligned along a single axis forming infinite one-dimensional channels. The framework decomposes just above 400 degrees C. Magnetic susceptibility data are consistent with weak antiferromagnetic ordering at low temperatures. (c) 2005 Elsevier Inc. All rights reserved.
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