Journal
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Volume 61, Issue 11-12, Pages 2708-2712Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2004.10.014
Keywords
charge-transfer; diazacrown ether; pi-acceptors; 1H NMR; IR; UV-vis spectra
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The interaction of the mixed oxygen-nitrogen cyclic base, N,N'-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooetadecane (DD18C6) with pi-acceptors such as picric acid (HPA) and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) has been studied spectrophotometrically in chloroform at 25 degrees C. The results obtained indicate the formation of 1:4 charge-transfer complexes with the general formula (DD18C6)(acceptor)(4). The electronic and infrared spectra of charge-transfer complexes along with the H-1 NMR spectra were recorded and discussed. Based on the data obtained, the complexes were formulated as [(DD18C6H(2))(HPA)(2)](PA)(2) and [(DD18C6H(2))(DDQ)(2)](DDQH)(2). A general mechanism explaining the formation of the DDQ complex has been suggested. (c) 2004 Published by Elsevier B.V.
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