Journal
COORDINATION CHEMISTRY REVIEWS
Volume 249, Issue 17-18, Pages 1937-1943Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2005.01.003
Keywords
Fenton reactions; organic substrates; aerated solutions
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There is only limited information about Fenton reactions involving organic substrates in oxygenated systems. In the presence of dioxygen, substrate radicals *R are generally converted rapidly into peroxyl radicals, *OOR, so that these radicals are the main reactive species in aerated aqueous systems under the majority of conditions. It is argued that the reactions of the peroxyl radicals with the transition metal complexes present in the solution are the key steps in determining the nature of the products and their yields. (c) 2005 Elsevier B.V. All rights reserved.
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