Journal
TETRAHEDRON
Volume 61, Issue 36, Pages 8598-8605Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2005.07.005
Keywords
organocatalysis; phosphines; conjugate addition; beta-dicarbonyl compounds
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Triphenylphosphine and tributylphosphine are excellent catalysts for Michael additions. Many beta-dicarbonyl compounds and electron-poor olefins, including sterically demanding partners, react successfully. The Michael addition catalyzed by phosphines deserves attention in its own right as a useful synthetic method. (c) 2005 Elsevier Ltd. All rights reserved.
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