Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 17, Pages 3405-3408Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200500261
Keywords
copper; helical structures; hydrogen bonds; Schiff bases; self-assembly; supramolecular chemistry
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An enantiopure ligand H2L [Schiff base prepared from (S)-(+)-2-phenylglycinol and 2-hydroxy-5-nitrobenzaldehyde] reacts with CUC1(2)(.)2H(2)O to yield a chiral copper complex [Cu(HL)Cl] (1) that forms right-handed supramolecular helices via O-(HCl)-Cl-...-Cu hydrogen bonds. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).
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