Journal
ORGANOMETALLICS
Volume 24, Issue 19, Pages 4503-4505Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om050619f
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The first isolable gold(I) fluoride complex, stabilized by an N-heterocyclic carbene (NHC) ligand, has been isolated in two-coordinate monomeric form. DFT calculations show significant p pi/d pi interactions between fluoride and gold(I) and indicate a substantial negative charge on fluorine.
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