4.6 Article

Au, Pd (mono and bimetallic) catalysts supported on graphite using the immobilisation method - Synthesis and catalytic testing for liquid phase oxidation of glycerol

Journal

APPLIED CATALYSIS A-GENERAL
Volume 291, Issue 1-2, Pages 210-214

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2005.01.044

Keywords

glycerol oxidation; gold; palladium; bimetallic catalyst; glyceric acid

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The selective oxidation of glycerol was performed using mono and bimetallic catalysts based on An and Pd and supported on graphite. Moreover, the preparation of bimetallic systems (Au-Pd) was investigated by using different procedures based on sol immobilisation method. The results showed that the use of a bimetallic system significantly improved the activity with respect to the monometallic system; whereas, the selectivity to glyceric acid showed to be dependent upon the reaction temperature and the preparation method used. (c) 2005 Elsevier B.V. All rights reserved.

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