Journal
ORGANIC LETTERS
Volume 7, Issue 19, Pages 4281-4283Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol051785m
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The weak base lithium 1,1,1,3,3,3-hexafluoroisopropoxide (LiHFI) is shown to be highly effective as a reagent for intermolecular Horner-Wadsworth-Emmons (HWE) olefination of epimerizable aldehydes with trimethyl phosphonoacetate, affording products with little or no epimerization and notably high E-selectivity.
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