Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 690, Issue 18, Pages 4192-4196Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2005.06.026
Keywords
palladium; pincer ligand; thioamide; luminescence
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Thioamide-based tridentate ligands, 1,3-benzenedicarbothioamides (1a-c), were used to afford pincer palladium(II) complexes (Pd(1-H)Cl, 2a-c) with eta(3)-S,C,S type coordination. The complexes exhibit strong emission in a glassy frozen state as well as in the solid state. The decay lifetime of the emission from the complexes is in a range of 8-9 x 10(-5) s, which is indicative of phosphorescent emission. (c) 2005 Elsevier B.V. All rights reserved.
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