Journal
ORGANIC LETTERS
Volume 7, Issue 19, Pages 4121-4124Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol051403c
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A stereocontrolled synthesis of the fully elaborated C-26-C-40 tricyclic [5,6,6]-bis-spiroacetal of spirastrellolide A containing the C-28 chlorine substituent is reported, exploiting asymmetric Sharpless dihydroxylation and boron-mediated allylation methodology.
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