Journal
ORGANIC LETTERS
Volume 7, Issue 19, Pages 4293-4296Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol051822+
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A new bifunctional binaphthyl-derived amine thiourea organocatalyst has been developed to promote enantioselective Morita-Baylis-Hillman reaction of cyclohexenone with a wide range of aldehydes. The process, catalyzed by the amine thiourea, affords synthetically valuable chiral allylic alcohol building blocks in high yields and high enantioselectivities.
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