Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 70, Issue 19, Pages 7578-7584Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo051039v
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Palladium hydroxide on carbon (Pearlman's catalyst) effectively catalyzes direct arylation reactions of aryl iodides and bromides, providing excellent arylation-to-hydrodehalogenation ratios (> 30:1) with broad scope for both intra- and intermolecular arylation processes. Studies aimed at determining the nature of the active catalyst indicate that an active homogeneous palladium species is produced under the reaction conditions.
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