4.5 Article Proceedings Paper

Electrical and mechanical properties of nanocomposites of single wall carbon nanotubes with PMMA

Journal

SYNTHETIC METALS
Volume 152, Issue 1-3, Pages 349-352

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.synthmet.2005.07.291

Keywords

carbon and related materials; solution processing; conductivity; insulating films; semiconducting films; Raman spectroscopy

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The electrical conductivity and mechanical characteristics of nanocomposites from pristine and doped single wall carbon nanotubes (SWNT) with polymethylmethacrylate (PMMA) were measured. In highly purified HiPCO SWNT, a percolation threshold as low as 0.17 weight percent has been found. The conductivity value at saturation is about 17 S/cm. If the purified HiPCO SWNTs are doped with SOCl2, the percolation threshold does not change but the saturation conductivity rises to about 100 S/cm. The mechanical properties were investigated for the PMMA composite mixed with SOCl2-doped SWNT. A small content of doped nanotubes dramatically changed Young modulus, toughness and tensile strength as well.

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