4.8 Article

ESI-MS studies on the mechanism of Pd(0)-catalyzed three-component tandem double addition-cyclization reaction

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 127, Issue 37, Pages 13060-13064

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja052588l

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Four cationic palladium intermediates have been characterized by the high-resolution ESI-FTMS technology, on the basis of which a mechanism was proposed for the Pd(0)-catalyzed three-component tandem double addition cyclization of organic halides, 2-(2,3-allenyl)malonates, and imines.

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