Journal
CATALYSIS LETTERS
Volume 103, Issue 3-4, Pages 191-193Publisher
SPRINGER
DOI: 10.1007/s10562-005-7153-7
Keywords
hydrocarboxylation; hydroxycarbonylation; aqueous biphasic systems
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Hydrosoluble palladium complexes with guanidinumphosphine ligands are active catalyst precursors for the hydrocarboxylation of styrene forming the corresponding carboxylic acids using water as a solvent. The aryl guanidinum derivative is much more stable than the alkyl derivative studied and provided high selectivity in the acids with conversions up to 96%.
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