Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 8, Issue 10, Pages 878-881Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2005.06.005
Keywords
palladium; methoxycarbonylation; alpha,omega-diesters; acrylic acids; phosphine
Categories
Ask authors/readers for more resources
The methoxycarbonylation of unsaturated acids or esters catalysed by Pd complexes of bis(ditertiarybutyl-phosphinomethyl)benzene (DTBPMB) produces alpha,omega-diesters with selectivities >95%, even if the double bond is deep in the chain or conjugated to the carbonyl group; unsymmetrical esters can also be produced with high selectivity. (c) 2005 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
