Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 347, Issue 11-13, Pages 1499-1503Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200505135
Keywords
allylic alcohols; allylic arenes; boronic acids; cross-coupling; palladium; water
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Palladium- catalyzed cross-coupling reactions of allylic alcohols and arylboronic acids in water are described. The reactions proceeded smoothly in water at reflux using catalytic amounts of [Pd(allyl)Cl](2) and PPh3. Addition of a catalytic amount of a base allowed the reaction to proceed even at lower temperatures.
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