Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 347, Issue 11-13, Pages 1533-1536Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200505175
Keywords
allylic alcohols; asymmetric catalysis; C-C bond formation; nickel; reductive coupling
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Nickel-catalyzed reductive coupling reactions of 1,3-enynes and aromatic aldehydes efficiently afford conjugated dienols in excellent regioselectivity and modest enantioselectivity when conducted in the presence of catalytic amounts of a monodentate, P-chiral ferrocenyl phosphine ligand. 1-(Trimethylsilyl) -substituted enynes are shown to be effective coupling partners in these reactions, and the dienol products thus formed readily undergo protiodesilylation under mild conditions.
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