4.1 Article

Spectroscopic challenges for high accuracy retrievals of atmospheric CO2 and the Orbiting Carbon Observatory (OCO) experiment

Journal

COMPTES RENDUS PHYSIQUE
Volume 6, Issue 8, Pages 876-887

Publisher

ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
DOI: 10.1016/j.crhy.2005.09.005

Keywords

carbon dioxide (CO2); Orbiting Carbon Observatory (OCO); near infrared spectroscopy

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The space-based Orbiting Carbon Observatory (OCO) mission will achieve global measurements needed to distinguish spatial and temporal gradients in the CO2 column. Scheduled by NASA to launch in 2008, the instrument will obtain averaged dry air mole fraction (X-CO2) with a precision of I part per million (0.3%) in order to quantify the variation of CO2 sources and sinks and to improve future climate forecasts. Retrievals Of X-CO2 from ground-based measurements require even higher precisions to validate the satellite data and link them accurately and without bias to the World Meteorological Organization (WMO) standard for atmospheric CO2 observations. These retrievals will require CO2 spectroscopic parameters with unprecedented accuracy. Here we present the experimental and data analysis methods implemented in laboratory studies in order to achieve this challenging goal.

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