Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 126, Issue 9-10, Pages 1361-1367Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2005.07.011
Keywords
fluorine; bromodifluoromethyl phenyl sulfone; difluoromethyl alcohol; 1,1-difluoro-1-alkene
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Tetrakis(dimethylamino)ethylene (TDAE) was found to be an effective electron-transfer agent that promoted the reactions of bromodifluoromethyl phenyl sulfone with aldehydes to give structurally diverse (benzenesulfonyl)difluoromethylated alcohols in good yield, which can be further transformed into difluoromethyl alcohols and 1,1-difluoro-1-alkenes via reductive desulfonylation and Julia olefination, respectively. (c) 2005 Elsevier B.V. All rights reserved.
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