Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 8, Issue 10, Pages 894-896Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2005.07.001
Keywords
rhodium catalysis; recoverable catalysts; stimulus sensitive catalysts; stimulus sensitive polymers
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We report the synthesis and characterization of a rhodium catalyst attached to a polymer which is designed to control catalyst reactivity in response to an applied stimulus. The catalyst precursor, Rh(Cl)(CO)(2)(NH2-polymer), was prepared from poly N-iso-propylacrylamide (pNIPAAm) and [Rh(Cl)(CO)(2)](2). The structure of the metal complex was interrogated using IR, Raman, UV/ Vis, NMR and XAFS, and catalytic activity was tested using an aqueous hydrogenation reaction. (c) 2005 Elsevier B.V. All rights reserved.
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