Journal
CHEMICAL & PHARMACEUTICAL BULLETIN
Volume 53, Issue 10, Pages 1366-1368Publisher
PHARMACEUTICAL SOC JAPAN
DOI: 10.1248/cpb.53.1366
Keywords
tert-leucine; N-phthaloylation; dirhodium(II) carboxylate; chiral catalyst
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An efficient and reliable procedure for the preparation of dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leucinate], Rh-2(S-PTTL)(4), a universally effective catalyst for a range of enantioselective carbene transformations, is described. The N-phthaloylation of (S)-tert-leucine by the method of Bose with essentially no racemization is a key to this process.
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