Equilibrium and kinetic modelling of Pb2+ biosorption by granulated agar extraction algal waste

An algal industrial waste from the agar extraction process was immobilized with an organic polymer (polyacrylonitrile, PAN) and used as a biosorbent for Pb2+ removal from aqueous solutions. The effects of the initial concentration, stirring velocity and particles diameter on Pb2+ biosorption were investigated in a batch system in order to explain the adsorption mechanism. Uptake kinetics follows the second-order Lagergren model and equilibrium is well described by the Langmuir isotherm. Maximum biosorption capacity of the composite material was found to be 20.5 +/- 0.8 mg Pb2+/g. Kinetic constants vary with the initial metal concentration. The adsorptive behaviour of biosorbent particles was modelled using a batch reactor mass transfer kinetic model. The model successfully predicts Ph2+ concentration profiles and provides significant insights on the biosorbent performance. The homogeneous diffusion coefficient (D-h) for particles with diameter between 0.5 < d(p) < 1 mm and for an initial concentration of 94 mg Pb2+/l solution was found to be 3.2 x 10(-8) cm(2) s(-1). (c) 2005 Elsevier Ltd. All rights reserved.