Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 26, Issue 19, Pages 1532-1537Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200500437
Keywords
charge density; cyclic voltammetry; ionization potential; oligofluorenes
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Electrochemical properties of monodisperse oligofluorenes (OFn, n = 2 to 7) and corresponding polyfluorene were studied by cyclic and differential pulse voltammetry. In combination with data of UV-vis absorption spectra, a series of linear relations such as the band gap, the oxidation potential, the ionization potential, and the electron affinity with the reciprocal number of the fluorene units (1/n) were deduced. When a chain length of ca. 14 repeat units is reached, a stable structure of about one positive charge per 3.5 repeat units is obtained.
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