Journal
TETRAHEDRON LETTERS
Volume 46, Issue 41, Pages 7023-7027Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.08.040
Keywords
oxidation of alcohol; mono-substituted Keggin-polyoxometalate; hydrogen peroxide; biphasic catalysis
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Mono-substituted Keggin-polyoxymetalate complex Na-6 [SiW11ZnH2O40]-12H(2)O was demonstrated to be an effective catalyst for the selective oxidation of alcohols in the presence of hydrogen peroxide as oxidant. The reaction was carried out in an aqueous/oil biphasic system, which allowed easy recovery of catalyst, under relative mild conditions. The catalyst could be reused five times without appreciable loss of activity. (c) 2005 Elsevier Ltd. All rights reserved.
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